Hallo again,
first of all thanks for this first tip - I got the device running correct in the EB-006 with the internal clock settings - at least I think its running on the internal clock, because the LED blinks even without the quarz on the EB-006 board

and this independent of RC or XTAL setting of the switch of the EB-006 board.
One more question about using the pic with his internal clock setting outside the EB-006 environment:
So now I took the chip out of the card and put it on a very simple circuit just putting
5V to pin 14
Gnd to pin 5
and I connected a Resistor (470 Ohm) to a LEDs Anode to pin 17 the LEDs Kathode to Gnd.
I expected that the LED would blink the same way as the EBlock EB004's LED was blinking in the EB006 environment - but surprise : nothing happens ... the LED is not activated or sometimes blinks just one time then nothing happens anymore ...
What do I do wrong ?
Is there a rule about other unused pin's (ground all unused pins or something like this ?)
Thanks for some more information for a pic newbie
Best regards